Pentamethylcyclopentadienyl-indium(I) and -Indium(III) Compounds-- Syntheses, Reactivities and X-Ray Diffraction and Electron Diffraction Studies of In(C5Me5)
STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY
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The golden yellow compound InC5Me5 has been prepared in only 62 yield from InC1 and LiC5Me5 in diethyl ether and fully characterized according to its physical and solubility properties, its reaction with dilute aqueous HC1, a cryoscopic molecular weight study in cyclohexane, IR and 1H NMR spectroscopic properties, a single crystal X ray diffraction study and a gas phase electron diffraction study. The other products of this reaction have been identified as InC5Me52C1, indium metal and C5Me52 in 5.0, 21 and 2.5 yields, respectively. Keywords Indium, Cyclopentadienyl-indiumI chemistry, Pentamethylcyclopentadienyl compounds, X ray structural study, Electron diffraction study.
- Organic Chemistry