Accession Number:

ADA196645

Title:

Grafting of Living Polymers from Activated Polysilanes

Descriptive Note:

Technical rept. no. 7, Aug 1987-Jul 1988

Corporate Author:

CARNEGIE-MELLON UNIV PITTSBURGH PA DEPT OF CHEMISTRY

Report Date:

1988-07-15

Pagination or Media Count:

4.0

Abstract:

Polysilanes with pendant triflate groups which were prepared by the dearylation process were used as backbones for preparation comblike graft copolymers. Two systems are described grafting polytetrahydrofuran from polysilanes and group transfer polymerization of methylmethacrylate initiated by silyl ketene acetals coupled to polysilane backbone. Keywords Polysilanes, Graft copolymers, Silanes.

Subject Categories:

  • Organic Chemistry
  • Polymer Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE