Accession Number:

ADA191252

Title:

Enhanced Oxidation and Solvolysis Reactions in Chemically Inert Microheterogeneous Systems.

Descriptive Note:

Interim rept. no. 5, Jan-Sep 87,

Corporate Author:

ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (SWITZERLAND)

Personal Author(s):

• Braun, Andre M.

Report Date:

1987-10-24

Pagination or Media Count:

12.0

Abstract:

In the second year of contract, the following parts of the original project have been accomplished 1. Model calculations of the kinetics of the decomposition of H2O2 in H2O and fitting of the model of sequence and rates of reactions to the experimental results. 2. Synthesis of perfluoro 2-methyl-2-propanol 3. Formulation of microemulsions containing totally perfluorinated components -sodium perfluorocaprylate - perfluoro n-hexane -perfluoro 2-methyl-2-pentanol or perfluoro t-butanol - water.

Descriptors:

• *OXIDATION
• *SOLVOLYSIS
• *REACTION KINETICS
• *HYDROGEN PEROXIDE
• *PROPANOLS
• *EMULSIONS
• CHEMICAL REACTIONS
• DECOMPOSITION
• SODIUM
• WATER
• SYNTHESIS(CHEMISTRY)
• FLUORINATED HYDROCARBONS
• HEXANES
• PENTANOLS
• BUTANOLS

Subject Categories:

• Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE