Accession Number:

ADA190041

Title:

Sequential Excitation Preparation of Molecular Energy Levels with Special Structural and Chemical Properties.

Descriptive Note:

Final rept. 1 Oct 84-31 Oct 87,

Corporate Author:

MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1987-12-31

Pagination or Media Count:

28.0

Abstract:

Research Objectives 1 Apply the Stimulated Emission Pumping SEP technique to highly excited vibrational levels of H2CO and D2CO. 2 Discover whether the rotation-vibration levels of H2COD2CO remain well organized at chemically significant levels of vibrational excitation. 3 Develop new multiple resonance spectroscopic techniques capable of measuring rotational energy transfer rates RET in highly excited vibrational levels of H2CO. 4 Develop statistical diagnostics for quantum ergodicity which are applicable to real SEP spectra of H2COD2CO. Keywords Spectroscopy, Vibrational structure, Optical-optical double resonance, Molecular dynamics, Anharmonic vibrational constants, Electric dipole moment, Coriolis perturbations.

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE