Accession Number:
ADA190041
Title:
Sequential Excitation Preparation of Molecular Energy Levels with Special Structural and Chemical Properties.
Descriptive Note:
Final rept. 1 Oct 84-31 Oct 87,
Corporate Author:
MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY
Personal Author(s):
Report Date:
1987-12-31
Pagination or Media Count:
28.0
Abstract:
Research Objectives 1 Apply the Stimulated Emission Pumping SEP technique to highly excited vibrational levels of H2CO and D2CO. 2 Discover whether the rotation-vibration levels of H2COD2CO remain well organized at chemically significant levels of vibrational excitation. 3 Develop new multiple resonance spectroscopic techniques capable of measuring rotational energy transfer rates RET in highly excited vibrational levels of H2CO. 4 Develop statistical diagnostics for quantum ergodicity which are applicable to real SEP spectra of H2COD2CO. Keywords Spectroscopy, Vibrational structure, Optical-optical double resonance, Molecular dynamics, Anharmonic vibrational constants, Electric dipole moment, Coriolis perturbations.
Descriptors:
- *CHEMICAL PROPERTIES
- *DIAGNOSIS(GENERAL)
- *MOLECULAR ENERGY LEVELS
- *MOLECULAR PROPERTIES
- *VIBRATION
- CONSTANTS
- CORIOLIS EFFECT
- DIPOLES
- DYNAMICS
- ELECTRIC MOMENTS
- EMISSION
- ERGODIC PROCESSES
- EXCITATION
- PERTURBATIONS
- PREPARATION
- PUMPING
- QUANTUM THEORY
- SEQUENCES
- SPECTROSCOPY
- STATISTICS
- STIMULATION(GENERAL)
- STRUCTURAL PROPERTIES
Subject Categories:
- Physical Chemistry