Accession Number:

ADA183701

Title:

Preparation and Characterization of Molecule-Based Transistors with a 50 Nanometer Source-Drain Separation Using Shadow Deposition Techniques: Towards Faster, More Sensitive Molecule-Based Devices.

Descriptive Note:

Technical rept.,

Corporate Author:

MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY

Personal Author(s):

• Jones,E. T.
• Chyan,Oliver M.
• Wrighton,Mark S.

Report Date:

1987-08-05

Pagination or Media Count:

15.0

Abstract:

Preparation of Au microelectrode arrays having spacings of 50-100 nm and available electrode areas of 10 to the -7th power sq cm is described. The dimensions are qualitatively smaller than previously reported and lead directly to faster switching and smaller switching energy for molecule-based transistors. Such microelectrodes can be functionalized with redox active polymers by oxidation of aniline to give polyaniline or by electrochemically assisted deposition of N,N-bisp-trimethoxysilylbenzyl-4,4-bipyridinium promoting Si-OMe hydrolysis to give the redox polymer BPQ2n. The fabrication procedure begins with a microelectrode array consisting of eight, individually addressable AU microelectrodes each approx. 50 micron long x approx 2.5 micron wide x approx. 0.1 micron thick with a spacing of approx. 1.5 micron between the microelectrodes.

Descriptors:

• *ELECTRODES
• *FABRICATION
• *TRANSISTORS
• MICROELECTRONICS
• ANILINES
• DEPOSITION
• DRAINAGE
• ELECTRODES
• ENERGY
• FABRICATION
• OXIDATION
• OXIDATION REDUCTION REACTIONS
• POLYMERS
• SEPARATION
• SHADOWS
• SOURCES
• SWITCHING

Subject Categories:

• Electrical and Electronic Equipment
• Solid State Physics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE