Electrochemistry of Sulfur, Na2S, S2, S2Cl2 and CS2 in 1-Methyl-3-Ethylimidazolium Chloride-Aluminum Chloride Melts.
Interim rept. Jun-Aug 86,
FRANK J SEILER RESEARCH LAB UNITED STATES AIR FORCE ACADEMY CO
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The electrochemical behavior of sulfur, sodium sulfide, sulfur monochloride and carbon disulfide was studied on a glassy carbon electrode at 25 C in 1-methyl-3-ethylimidazolium chloroaluminate melts in basic excess organic chloride, neutral 11 mole ratio of organic chloride and AlCl 3 regions. Cyclic voltammetry, rotating disk electrode and steady-state potentiostatic techniques were used in the study. The literature on sulfur and sulfur compounds in NaCl-AlCl3 melts is reviewed and comparisons are made with the room temperature melts.
- Physical Chemistry