Accession Number:

ADA156997

Title:

A Procedure Identifying a Polyacetylene Initiator of Olefin Metathesis. The Reactivities of Metal-Carbenes Toward Alkenes and Alkynes.

Descriptive Note:

Technical rept.,

Corporate Author:

COLUMBIA UNIV NEW YORK DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1985-07-10

Pagination or Media Count:

63.0

Abstract:

FWhen phenylacetylene plus tungsten hexachloride initiate the metathesis of cyclopentene, polyphenylacetylene is found attached to the resulting polypentenamer chains. The average amount of this polyphenylacetylene does not vary as the growth of the polypentenamer chains is checked by added diphenylacetylene, showing it to be present as a block at their start. The implication is that the metathesis is initiated by the growning acetylene writing with the olefin, strong evidence for the hypothesis that the acetylene polymerizatrion is propagated by metal-carbenes. The variations that occur in the length of the chains and the amount of polyphenylacetylene attached to the average chain as the acetylene concentration is varied are analyzed for the underlying kinetic parameters. The stabilized metal-carbenes propagating the phenylacetylene polymerization react 3,000 times more quickly with phenylacetylene than with cyclopentene, whereas the less stabilized metal-carbenes propagating the cyclopentene, metathesis select 17-fold in the opposite direction. Diphenylacetylene is 26 times more effective than phenylacetylene in quenching the metathesis, and 2.4 times more effective than phenylmethylacetylene. The key to the experiments is the observation that diphenylacetylene in minute amounts quenches metathesis but does not initiate the reaction.

Subject Categories:

  • Polymer Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE