Irida-, Rhoda-, Nickela-, and Cuprapentaboranes Derived from the arachno-(B4H9)(-) Ion. Crystal Structure of Iridaborane Complex One Butadiene Complex, an Analogue of arachno-B5H11 and Iridium Complex One Three Butadiene Complex Cation,
OHIO STATE UNIV COLUMBUS DEPT OF CHEMISTRY
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The development of a simple synthesis of B4H10 has made available a potentially convenient route to metallapentaboranes by reaction of the B4H9- ion with suitable transition-metal complexes. This report describes the synthesis and characterization of four metallapentaboranes derived from B4H9-. Originator-supplied keywords include Iridium compounds, Rhodium compounds, Boranes, Nickel compounds, and Crystal structure.
- Inorganic Chemistry