Accession Number:

ADA148811

Title:

Dioxododecaisopropoxytetratungsten. Oxygen Atom Abstraction from Acetone in Reactions with Hexaisopropoxyditungsten (M=M).

Descriptive Note:

Technical rept.,

Corporate Author:

INDIANA UNIV AT BLOOMINGTON DEPT OF CHEMISTRY

Report Date:

1984-11-29

Pagination or Media Count:

9.0

Abstract:

Hexaisopropoxyditungsten W2OPri6py2 M-M Triple bond and acetone 1 equiv react in hydrocarbon solvents and ambient temperatures to yield tetramethylethylene and Dioxododecaisopropxytetratungsten W4O2OPri12 which is shown, by x-ray study, to be an unusual cluster type in which the 8 electrons available for M-M bonding are partitioned to a M-M triple and M-M single bond.

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE