Dioxododecaisopropoxytetratungsten. Oxygen Atom Abstraction from Acetone in Reactions with Hexaisopropoxyditungsten (M=M).
INDIANA UNIV AT BLOOMINGTON DEPT OF CHEMISTRY
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Hexaisopropoxyditungsten W2OPri6py2 M-M Triple bond and acetone 1 equiv react in hydrocarbon solvents and ambient temperatures to yield tetramethylethylene and Dioxododecaisopropxytetratungsten W4O2OPri12 which is shown, by x-ray study, to be an unusual cluster type in which the 8 electrons available for M-M bonding are partitioned to a M-M triple and M-M single bond.
- Inorganic Chemistry
- Organic Chemistry