Accession Number:

ADA148803

Title:

Synthesis and Reactivity of (Bis(trimethylsilyl)Methylene)(Mesityl)Phosphine.

Descriptive Note:

Techncial rept.,

Corporate Author:

TEXAS CHRISTIAN UNIV FORT WORTH DEPT OF CHEMISTRY

Report Date:

1984-12-12

Pagination or Media Count:

26.0

Abstract:

Two recent papers have described the synthesis and characterization of a series of P-mesityl substituted phosphorus compounds containing Si-N-P andor Si-C-P linkages. These systems are of interest, in part, as precursors to new types of low-coordinate phosphorus compounds including methylene phosphines, RP-CR2 double bond, and imino methylene phosphoranes, RP-NR-CR2 double bonds. As an extension of these studies, we report here the synthesis and some derivative reactions of bisTrimethylsilylmethylenemesitylphosphine.

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE