Homogeneous Reaction Involving Components of Different Redox Couples. I. Theoretical Considerations and Digital Simulation.
UTAH UNIV SALT LAKE CITY DEPT OF CHEMISTRY
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Coupled heterogeneous electron transferhomogeneous reactions occur in the electro-oxidation of certain anilines, and in association reactions of hydrocarbon anions with metal cations. If the adduct A sub m sub R is electroinactive, the resulting voltammogram is distorted in a way which is characteristic of the value of m. The derivation of the theoretical fluxes for these reactions and calculated normal potential pulse voltammograms are presented. The results are derived from both limiting flux and digital simulation considerations. Author
- Physical Chemistry
- Numerical Mathematics