Synthesis and Structure of Sulfur Derivatives of a (Methylene)phosphine.
Technical rept. for period ending 1983,
TEXAS CHRISTIAN UNIV FORT WORTH DEPT OF CHEMISTRY
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The methylenephosphine MesP C SiMe32 1, Mes mesityl is smoothly oxidized by elemental sulfur to the 3-membered is smoothly oxidized by elemental sulfur to the 3-membered ring system MesPS-S-CSiMe32 3 which, upon treatment with n-Bu3P, is converted to the 3-coordinate phosphorane MesPSCSiMe32 2. The nearly isostructural nature of compounds 2 and 3 is confirmed by their x-ray crystallographic analyses. Author
- Inorganic Chemistry
- Organic Chemistry