Accession Number:

ADA141502

Title:

A Twisted P-C Double Bond: Synthesis and Structure of a (Methylene)phosphine Fe(C0)4 Complex.

Descriptive Note:

Technical rept. for period ending 1983,

Corporate Author:

TEXAS CHRISTIAN UNIV FORT WORTH DEPT OF CHEMISTRY

Report Date:

1984-05-18

Pagination or Media Count:

11.0

Abstract:

The reaction of Me3Si2CPCl with LINSiMe32 affords the tetrasilylated aminomethylenephosphine 1 which, reacts smoothly with Fe2CO9 yielding the eta super 1 complex Me3Si2CPFeCO4-NSiMe32 2. X-ray crystallographic analysis of 2 reveals an unusual coordination of the phosphine ligand in an equatorial position as well as a short 1,657 A, but severely twisted 30.3 deg, P C double bond. Author

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE