Accession Number:
ADA141502
Title:
A Twisted P-C Double Bond: Synthesis and Structure of a (Methylene)phosphine Fe(C0)4 Complex.
Descriptive Note:
Technical rept. for period ending 1983,
Corporate Author:
TEXAS CHRISTIAN UNIV FORT WORTH DEPT OF CHEMISTRY
Personal Author(s):
Report Date:
1984-05-18
Pagination or Media Count:
11.0
Abstract:
The reaction of Me3Si2CPCl with LINSiMe32 affords the tetrasilylated aminomethylenephosphine 1 which, reacts smoothly with Fe2CO9 yielding the eta super 1 complex Me3Si2CPFeCO4-NSiMe32 2. X-ray crystallographic analysis of 2 reveals an unusual coordination of the phosphine ligand in an equatorial position as well as a short 1,657 A, but severely twisted 30.3 deg, P C double bond. Author
Descriptors:
Subject Categories:
- Inorganic Chemistry
- Organic Chemistry