Gas-Liquid Correlation of Ionization Energies.
NEW YORK UNIV NY DEPT OF CHEMISTRY
Pagination or Media Count:
Ionization potentials of ions and molecules are correlated with the threshold energies of their aqueous solutions for photoelectron emission. Inner- and outer-sphere reorganizations are treated, respectively, in terms of a discrete number of dipoles and a continuous medium model. Calculated and experimental threshold energies are compared for halides and hydroxide ions and water. The threshold and reorganization energies of the hydrated electron are calculated from threshold energies of anions and their absorption spectra for charge transfer to the solvent. Author
- Atomic and Molecular Physics and Spectroscopy