Accession Number:

ADA135507

Title:

Binuclear Schiff Base Complexes of m-Xylylenebis(2-(1,3-Propanedi (2-Pyridinealdmine))) and M-Xylylenebis(2-(1,3-Propanedi(2-Pyrrolealdmine))).

Descriptive Note:

Technical rept.,

Corporate Author:

ROCHESTER UNIV NY DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1983-11-04

Pagination or Media Count:

16.0

Abstract:

Binulcear complexes of Ni, Cu, and Co have been synthesized and characterized. The reaction of nickelII-, copper II-, or cobaltIIchloride with a solution of 2-pyridinealdehyde and m-xylylenebis2-2,3-propanediamine results in the formation of Ni2LC142a, Cu2LC14 3 and Co2LC144, respectively, where L m-xylylenebis2-2,3-propanedi2-pyridinealdimine. The binuclear nickel complexes, Ni2LN34 2b and Ni2LSCN4 2c are prepared by metathesis of the chloride ion of complex 2a using the appropriate sodium salt. These complexes, 2-4, exhibit electronic spectra consistent with tetragonally distorted six-coordinate complexes.

Subject Categories:

  • Inorganic Chemistry
  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE