Comparison of Autoionization and Photoelectron Spectra of CO.
GEORGE WASHINGTON UNIV WASHINGTON D C DEPT OF CHEMISTRY
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Photoelectron spectra and the autoionization portion of the Auger spectra are compared for CO. Eight final states of the photoelectron spectra coincide with those of the autoionization spectra three of them are the well-known one-hole states and the other five are two-hole-one-electron states. A photoelectron band at 27.4eV is identified for the first time by its exact match to the stongest band of the autoionization spectra. The symmetries of these and other two-hole-one-electron states are induced by comparing the intensities of X-ray and UV photoelectron spectra. Author
- Atomic and Molecular Physics and Spectroscopy