The Reaction of CH3O2 with NO.
Final rept. 28 Sep 78-27 Sep 80,
PENNSYLVANIA STATE UNIV UNIVERSITY PARK IONOSPHERE RESEARCH LAB
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The kinetics of reaction 1, CH302 N0 yield CH30 N02 were studied in the temperature range of 218deg K to 365deg K using the flash photolysis of C12 in the presence of CH4 and 02 as a source of CH302 radicals. These radicals were monitored by ultraviolet absorption. The rate coefficient k sub 1 2.1 or - 1 x 10 to the minus 12th power exp380 or - 250Tcu cm per sec at 200 Torr total pressure. The reaction is independent of pressure 70 - 600 Torr, mostly CH4 at 296deg K.
- Organic Chemistry