Electrogenerated Chemiluminescence. 42. The Electrochemistry and Electrogenerated Chemiluminescence of the Tris(2,2'-bipyrazine)ruthenium(II) System.
Technical rept. 1 Sep 82-31 Aug 83,
TEXAS UNIV AT AUSTIN DEPT OF CHEMISTRY
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The electrochemical behavior and electrogenerated chemiluminescence ecl of of Rubpz32 as the PF6- salt in acetonitrile solutions was investigated. Oxidation to the 3 form and reduction to the 1, 0, -1 and -2 forms occur at potentials about 0.5V more positive than the corresponding bipyridine complex. Emission characteristic of Rubbpz32 is produced upon the electron transfer reaction between the 3 and 1 species. Weak emission also results from reaction of the 3 species with solvent or impurities. Author
- Atomic and Molecular Physics and Spectroscopy