Accession Number:

ADA125531

Title:

A Microscopic Model for the Liquid Metal - Ionic Solution Interface.

Descriptive Note:

Interim technical rept.,

Corporate Author:

PUERTO RICO UNIV RIO PIEDRAS DEPT OF PHYSICS

Report Date:

1983-02-10

Pagination or Media Count:

30.0

Abstract:

A microscopic model for the metal-solution interface is presented, which for the first time, includes both a non-ideal treatment of the metal and a molecular model for the solution side. The metal is described by a jellium including electron-ion-pseudopotential. The solution is treated as a mixture of hard spheres with point dipoles solvent molecules or point charges ions. The statistical mechanics is solved using the mean spherical approximation. No a priori separation is introduced between compact and diffuse layers. A simplified version of the model is applied to the case of Hg-DMSO systems. Author

Subject Categories:

  • Metallurgy and Metallography
  • Atomic and Molecular Physics and Spectroscopy
  • Nuclear Physics and Elementary Particle Physics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE