Accession Number:

ADA114726

Title:

Cofacially Linked Metallomacrocyclic Conductive Polymers. Halogen Dopant Level and Macromolecule Architecture, Electronic Structure, and Charge Transport.

Descriptive Note:

Interim rept.,

Corporate Author:

NORTHWESTERN UNIV EVANSTON IL DEPT OF CHEMISTRY

Report Date:

1981-12-23

Pagination or Media Count:

7.0

Abstract:

This paper presents an integrated study of the nature of the halogen doping process for the cofacially joined electrically conductive metallomacrocyclic polymers MPcOn, M equal Si,Ge,Sn Pc equal phthalocyaninato. The properties of the MPcObryn and MPcOIyn materials have been studied in detail as a function of y by X-ray diffractometry, infrared, optical, resonance Raman, EPR, four-probe van der Pauw, and static magnetic susceptibility. All data are in accord with a principally heterogeneous doping process. The sensitivity of the physical properties to M and interplanar ring-ring spacing is clearly evident. Author

Subject Categories:

  • Plastics
  • Electricity and Magnetism
  • Nuclear Physics and Elementary Particle Physics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE