Accession Number:

ADA101168

Title:

Synthesis of New Inorganic and Organometallic Materials.

Descriptive Note:

Final rept. 1 Oct 76-31 Mar 81,

Corporate Author:

BRISTOL UNIV (ENGLAND) DEPT OF INORGANIC CHEMISTRY

Personal Author(s):

Report Date:

1981-04-23

Pagination or Media Count:

35.0

Abstract:

This report describes several research projects in organometallic chemistry. New methods are reported for preparing heteronuclear metal cluster complexes with osmium-platinum, -nickel, -rhodium, and -iron bonds. Reactions between platinum compounds and nido-carbaboranes yield new cage carbaplatina-boranes. The activation of acetylenes by nickel, molybdenum and platinum has been shown to give many novel organometal structures, and the results emphasize the role of dimetal complexes in reactivity patterns. New fluorocarbon complexes of platinum and molybdenum are also described. Author

Subject Categories:

  • Organic Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE