Accession Number:

ADA099647

Title:

Oxotrimolybdenum (IV) Alkoxides: Mo3(micron 3-O)(micron 3-OR)(micron 2-OR)3(OR)6, Where R = i-Pr and CH2CMe3 - from Serendipitous Discovery to Total Synthesis.

Descriptive Note:

Technical rept.,

Corporate Author:

INDIANA UNIV AT BLOOMINGTON DEPT OF CHEMISTRY

Report Date:

1981-05-18

Pagination or Media Count:

12.0

Abstract:

OxotrimolybdenumIV alkoxides, Mo30OR10 where R isopropyl and nepoentyl, have been discovered and are shown to be related to a rapidly emerging class of triangulo early transition metal complexes recently reported by Cotton and coworkers. A high yield synthesis of the new compounds is described and involves the addition of an oxomolybdenum6 unit across a Mo Triple Bond Mo bond. Author

Subject Categories:

  • Inorganic Chemistry
  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE