Accession Number:

ADA099417

Title:

The Synthesis and Characterization of 1,1-(P(C6H5)3)2-1-H-1,2,4-RhC2B10H12: A Supraicosahedral Metallocarborane Catalyst Precursor.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1981-02-04

Pagination or Media Count:

16.0

Abstract:

The 13-vertex supraicosahedral metallocarborane 1,1-PC6H532-1-H-1,2,4-RhC2B10H12, a hydrogenation catalyst precursor, has been synthesized through routes analogous to 10-,11-, and 12-vertex phosphinorhodacarborane formation, and characterized by NMR studies and an X-ray diffraction crystal structure analysis. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE