Accession Number:

ADA093726

Title:

Photoelectron Emission Spectroscopy of Inorganic Cations in Aqueous Solution.

Descriptive Note:

Technical rept.,

Corporate Author:

NEW YORK UNIV N Y DEPT OF CHEMISTRY

Report Date:

1980-12-01

Pagination or Media Count:

22.0

Abstract:

Threshold energies 6.1 less than E sub t equal to or lesser than 8.6 eV are determined for photoelectron emission by 16 inorganic cations in aqueous solution. E sub ts are correlated with gas-phase ionization potentials, solvation and reorganization free energies, standard reduction potentials and ligand field stabilization energies five transition metals. Dielectric saturation is shown to drastically lower threshold energies. Author

Subject Categories:

  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE