Accession Number:

ADA090779

Title:

A Reinvestigation of the Claim that Stannocene and h5-Cyclopentadienyltricarbonyltungsten Hydride Form Bis-(h5-cyclopentadienyltricarbonyltungsten) tin (II).

Descriptive Note:

Technical rept.,

Corporate Author:

OKLAHOMA UNIV NORMAN DEPT OF CHEMISTRY

Personal Author(s):

• Dory,T. S.
• Zuckerman,J. J.
• Huff,C. D.
• Connolly,J. W.

Report Date:

1980-10-15

Pagination or Media Count:

9.0

Abstract:

Reinvestigation of the claim that stannocene and h5-cyclopentadienyltricarbonyltungsten hydrige form bis-h5-cyclopentadienyltricarbonyltungsten tinII, the sole representative of a class of compounds in which tinII is attached to electropositive ligands, is revealed to be the facile halogenation product from the recrystallization fromhalocarbons of the tris-h5-cyclopentadienyltricarbonyltungstentinIV hydride which actually results from the action of the stannocene on the tungsten hydride. The tris-h5-cyclopentadienyltricarbonyltungstentinIV hydride, chloride, bromide and iodide are reported.

Descriptors:

• *SYNTHESIS(CHEMISTRY)
• *ORGANOMETALLIC COMPOUNDS
• *TIN COMPOUNDS
• *CARBONYL COMPOUNDS
• *PENTADIENES
• HYDRIDES
• TRANSITION METALS
• NUCLEAR MAGNETIC RESONANCE
• MASS SPECTROSCOPY
• MOSSBAUER EFFECT
• HALOGENATION
• PHENYL RADICALS
• INFRARED SPECTRA
• TUNGSTEN COMPOUNDS
• CYCLOPENTANES

Subject Categories:

• Organic Chemistry
• Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE