Accession Number:

ADA090555

Title:

Chemical Reactivity of Cyanogen Chloride in Aqueous Solution.

Descriptive Note:

Quarterly status rept. no. 2, 1 Dec 71-29 Feb 72,

Corporate Author:

BROWN UNIV PROVIDENCE RI

Personal Author(s):

• Edwards,John O.
• Sauer,Maria

Report Date:

1973-01-01

Pagination or Media Count:

16.0

Abstract:

Studies of the chemical reactivity of cyanogen chloride with various nucleophiles in aqueous solutions were continued. Spectrophotometric techniques, as well as the colorimetric technique described in the previous report, were used for analysis. Nucleophiles investigated were pyridine, piperidine, trimethylamine, -picoline, sec-butylamine, acetaldoxime, and hydriodic acid. A Bronsted plot with all nucleophiles thus far studies is included. Author

Descriptors:

• *AMINES
• *CHEMICAL REACTIONS
• *CHLORIDES
• *CYANOGEN
• METHYLAMINE
• REACTION KINETICS
• SOLUTIONS(MIXTURES)
• CONSTANTS
• BUTYL RADICALS
• ABSORPTION SPECTRA
• PH FACTOR
• PYRIDINES
• COLORIMETRY
• ALKALINITY
• BASES(CHEMISTRY)
• DISTILLATION
• BUFFERS(CHEMISTRY)
• SPECTROPHOTOMETERS
• PIPERIDINES

Subject Categories:

• Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE