Accession Number:

ADA089694

Title:

Organometallic Phosphazenes: Synthesis and Rearrangement of Propynyl and Propadienyl Cyclotriphosphazenes.

Descriptive Note:

Interim technical rept.,

Corporate Author:

PENNSYLVANIA STATE UNIV UNIVERSITY PARK DEPT OF CHEMISTRY

Report Date:

1980-09-22

Pagination or Media Count:

47.0

Abstract:

Copper- or lithiophosphazene anions react with prop-2-ynyl bromide with the attachment fo the prop-2-ynyl group to the ring. Subsequent rearrangements yielded prop-1,2-dienyl or prop-1-ynyl derivatives. The mechanism of these reactions is discussed. These model reactions are of considerable significance for the analogous polymeric substitutions. Author

Subject Categories:

  • Polymer Chemistry
  • Plastics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE