Organometallic Phosphazenes: Synthesis and Rearrangement of Propynyl and Propadienyl Cyclotriphosphazenes.
Interim technical rept.,
PENNSYLVANIA STATE UNIV UNIVERSITY PARK DEPT OF CHEMISTRY
Pagination or Media Count:
Copper- or lithiophosphazene anions react with prop-2-ynyl bromide with the attachment fo the prop-2-ynyl group to the ring. Subsequent rearrangements yielded prop-1,2-dienyl or prop-1-ynyl derivatives. The mechanism of these reactions is discussed. These model reactions are of considerable significance for the analogous polymeric substitutions. Author
- Polymer Chemistry