Synthesis and Characterization of Metallo-Organic Conducting Materials with Tetraazaannulenes.
NORTH CAROLINA UNIV AT CHAPEL HILL DEPT OF CHEMISTRY
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Compounds of the macrocyclic ligand 4,11-dihydro-dibenzob,i1,4,8,11tetraaza14annulene, dB-TAA, have been prepared with Cu2, Ni2, Co2, Pd2, Pt2. The palladium complex crystallizes in two crystalline modifications, one of which is similar to the structurally characterized compound NidB-TAA, while the second form packs as cofacial dimers in the solid state.
- Physical Chemistry
- Polymer Chemistry