Accession Number:
ADA080167
Title:
Synthesis and Structure of a New Class of Metallophthalocyanato (pyridine or THF) - Ruthenium(II) and carbonylphthalocyanato (pyridine or THF)osmium(II).
Descriptive Note:
Interim rept.,
Corporate Author:
TEXAS A AND M UNIV COLLEGE STATION DEPT OF CHEMISTRY
Personal Author(s):
Report Date:
1980-01-01
Pagination or Media Count:
56.0
Abstract:
CarbonylphthalocyanatopyridinerutheniumII PcRuCO Py, carbonylphthalocyanatopyridineosmiumII PcOsCO Py, and carbonylphthalocyanato tetrahydrofuranrutheniumII PcRuCO THF were prepared in pure form. They are among the first reported metallophthalocyanines with a carbonyl as one of their axial ligands. Furthermore, several new ways of synthesizing these complexes in quantitative yields have been established. The structure of PCOsCO Py were elucidated by the X-ray diffraction analysis. Author
Descriptors:
Subject Categories:
- Organic Chemistry