Synthesis and Structure of a New Class of Metallophthalocyanato (pyridine or THF) - Ruthenium(II) and carbonylphthalocyanato (pyridine or THF)osmium(II).
TEXAS A AND M UNIV COLLEGE STATION DEPT OF CHEMISTRY
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CarbonylphthalocyanatopyridinerutheniumII PcRuCO Py, carbonylphthalocyanatopyridineosmiumII PcOsCO Py, and carbonylphthalocyanato tetrahydrofuranrutheniumII PcRuCO THF were prepared in pure form. They are among the first reported metallophthalocyanines with a carbonyl as one of their axial ligands. Furthermore, several new ways of synthesizing these complexes in quantitative yields have been established. The structure of PCOsCO Py were elucidated by the X-ray diffraction analysis. Author
- Organic Chemistry