Accession Number:

ADA080167

Title:

Synthesis and Structure of a New Class of Metallophthalocyanato (pyridine or THF) - Ruthenium(II) and carbonylphthalocyanato (pyridine or THF)osmium(II).

Descriptive Note:

Interim rept.,

Corporate Author:

TEXAS A AND M UNIV COLLEGE STATION DEPT OF CHEMISTRY

Personal Author(s):

• Tsutsui,M.
• Omiya,Shuichi

Report Date:

1980-01-01

Pagination or Media Count:

56.0

Abstract:

CarbonylphthalocyanatopyridinerutheniumII PcRuCO Py, carbonylphthalocyanatopyridineosmiumII PcOsCO Py, and carbonylphthalocyanato tetrahydrofuranrutheniumII PcRuCO THF were prepared in pure form. They are among the first reported metallophthalocyanines with a carbonyl as one of their axial ligands. Furthermore, several new ways of synthesizing these complexes in quantitative yields have been established. The structure of PCOsCO Py were elucidated by the X-ray diffraction analysis. Author

Descriptors:

• *SYNTHESIS(CHEMISTRY)
• *ORGANOMETALLIC COMPOUNDS
• *PHTHALOCYANINES
• *FURANS
• *PYRIDINES
• *CARBONYL COMPOUNDS
• *OSMIUM COMPOUNDS
• *RUTHENIUM COMPOUNDS
• COMPLEX COMPOUNDS
• X RAY DIFFRACTION
• MOLECULAR STRUCTURE
• DIFFRACTION ANALYSIS

Subject Categories:

• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE