Accession Number:

ADA080167

Title:

Synthesis and Structure of a New Class of Metallophthalocyanato (pyridine or THF) - Ruthenium(II) and carbonylphthalocyanato (pyridine or THF)osmium(II).

Descriptive Note:

Interim rept.,

Corporate Author:

TEXAS A AND M UNIV COLLEGE STATION DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1980-01-01

Pagination or Media Count:

56.0

Abstract:

CarbonylphthalocyanatopyridinerutheniumII PcRuCO Py, carbonylphthalocyanatopyridineosmiumII PcOsCO Py, and carbonylphthalocyanato tetrahydrofuranrutheniumII PcRuCO THF were prepared in pure form. They are among the first reported metallophthalocyanines with a carbonyl as one of their axial ligands. Furthermore, several new ways of synthesizing these complexes in quantitative yields have been established. The structure of PCOsCO Py were elucidated by the X-ray diffraction analysis. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE