Preparation and Properties of ((Trimethylsilyl)-methyl)-gallium(III) Compounds.
STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY
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A series of neutral organogalliumIII compounds which incorporate the trimethylsilylmethyl ligand, GaCH2SiMe3n X3-n n 3,2,1 X Cl, Br have been prepared and fully characterized by elemental analyses NMR and infrared spectroscopy, molecular weight data, solubility properties and Lewis acid-base chemistry. The parent compound GaCH2SiMe33 was prepared from GaCl3 by a standard Grignard reaction in diethylether. The halogen derivatives were prepared from GaCH2SiMe33 by elimination reactions with HCl or HBr and exchange reactions with GaCl3 or GaBr3.
- Polymer Chemistry
- Nuclear Physics and Elementary Particle Physics