Accession Number:

ADA073753

Title:

Synthesis and Molecular Structure of (3-(PPh3)-3,3-(NO3)-3,1,2-RhC2B9H11), a Versatile Metallocarborane Reagent.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1979-08-13

Pagination or Media Count:

17.0

Abstract:

The action of nitric acid or N02N204 mixture on 3,3-PPh32-3-H-3,1,2-RhC2B9H11 affords the nitratorhodacarborane 3-PPh -3,3-N03-3,1,2-RhC2B9H11 I whose structure has been determined by X-ray crystallography, triclinic, space group Pl, a 12.5925, b 16.3828, c 17.0596 degrees A, alpha 75.744 0 degrees, Beta 105.343 0 degrees, Gamma 120.053 0 degrees, Zeta 2. The latter species has been shown to be a useful precursor in the synthesis of other rhodacarborane derivatives. Author

Subject Categories:

  • Organic Chemistry
  • Atomic and Molecular Physics and Spectroscopy
  • Nuclear Physics and Elementary Particle Physics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE