Accession Number:

ADA064163

Title:

The Structure and Magnetic and Electrical Conductivity Properties of the Charge Transfer Compound 1,1'-Dimethylferrocenium Bis(Tetracyanoquinodimethane), (CH3C5H4)2FeTCNQ2.

Descriptive Note:

Technical rept.,

Corporate Author:

NORTH CAROLINA UNIV AT CHAPEL HILL DEPT OF CHEMISTRY

Personal Author(s):

• Wilson,Scott R.
• Corvan,Peter J.
• Seiders,Reginald P.
• Hodgson,Derek J.
• Brookhart, Maurice

Report Date:

1979-01-15

Pagination or Media Count:

12.0

Abstract:

The charge transfer compound 1,1-dimethylferrocenium bistetracyanoquinodimethane has been prepared and characterized by a single crystal x-ray structure determination, magnetic susceptibility studies, and conductivity measurements. The structure consists of chains of stacked TCNQ molecules and stacked ferrocenium ions, but there are no intermolecular interactions in the latter chains. Author

Descriptors:

• *COMPLEX COMPOUNDS
• *ORGANOMETALLIC COMPOUNDS
• *FERROCENES
• MAGNETIC PROPERTIES
• CRYSTAL STRUCTURE
• SYNTHESIS(CHEMISTRY)
• ELECTRICAL CONDUCTIVITY
• CHARGE TRANSFER

Subject Categories:

• Organic Chemistry
• Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE