Accession Number:

ADA061690

Title:

The Preparation of (NP(p-OC6H4Li)2)3 by Metal -Halogen Exchange, and Its Reactions with Electrophiles.

Descriptive Note:

Interim technical rept.,

Corporate Author:

PENNSYLVANIA STATE UNIV UNIVERSITY PARK DEPT OF CHEMISTRY

Personal Author(s):

• Evans,T. L.
• Fuller,T. J.
• Allcock,H. R.

Report Date:

1978-11-13

Pagination or Media Count:

5.0

Abstract:

The first example of a successful metal-halogen exchange reaction between n-butyllithium and a hexap-halogenophenoxycyclotriphosphazene is described. The hexalithio derivative was allowed to react with electrophiles to yield carboxylic acid, stannane, and phosphine-derivatives. Author

Descriptors:

• *ORGANOMETALLIC COMPOUNDS
• *CHEMICAL REACTIONS
• *BUTYL RADICALS
• *PHOSPHAZENE
• YIELD
• PHOSPHINE
• LITHIUM COMPOUNDS
• HALOGENS
• CARBOXYLIC ACIDS
• CHEMICAL DERIVATIVES
• STANNATES

Subject Categories:

• Polymer Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE