Accession Number:

ADA061590

Title:

Spectroscopic Investigation of the Origin of Distortion of Guest Coronene in Various Sites of n-Heptane Shpol'skii Matrix.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1978-10-01

Pagination or Media Count:

32.0

Abstract:

N-Heptane was chosen as a matrix because the spectra are sharp Shpolskii effect and because this lattice offers various modes of insertion to the aromatic as evidenced by a multiplet of at least five components, one of them occurring in polycrystals only. The measurement of the zero-field splitting parameters of the different sites which appear in the phosphorescence spectrum has shown that each site corresponds to a different distortion within the triplet state.

Subject Categories:

  • Organic Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE