Synthesis of Open-Chain Poly(Difluorophosphazene) and Its Reactions with Alkoxides, Aryloxides, and Amines.
PENNSYLVANIA STATE UNIV UNIVERSITY PARK DEPT OF CHEMISTRY
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The first preparation of soluble polydifluorophosphazene is described, together with its reactions with alkoxides, aryloxide, and amines. Amines replace only one fluorine per phosphorus. Mechanistic explanations are suggested on the basis of model compound reactions with cyclic phosphazenes. Author
- Polymer Chemistry