Synthesis and NMR Study of Ethyl- and Perfluoro-ethyltin Vinyl and Hydride Derivatives,
OKLAHOMA UNIV NORMAN DEPT OF CHEMISTRY
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The syntheses of four perfluorethyltin compounds are reported for the first time via a Barbier reaction from the corresponding ethyl- and vinyltin bromides. The synthetic reactions resulted in the iodide transhalogenation product in the ethyltin case and the vinyl group redistribution product in the vinyltin case as well as the expected products. The new compounds were characterized by infrared and mass spectral data, and studied by proton and fluorine-19 nmr.
- Inorganic Chemistry
- Organic Chemistry