Rational Synthesis of Unidimensional Mixed Valence Solids. Structure-Oxidation State-Charge Transport Relationships in Iodinated Nickel and Palladium Bisbenzoquinonedioximates.
NORTHWESTERN UNIV EVANSTON ILL DEPT OF CHEMISTRY
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The results of the present investigation indicate that the Mbqd2I0.50 materials, M Ni, Pd, are best formulated as Mbqd2I0.50.S materials where S represents various amounts of the aromatic solvent employed for crystallization. As deduced from resonance Raman, I-129 Mossbauer, and diffuse x-ray scattering measurements, the iodine is present as I3-, and thus the mbqd2I0.50.S materials are indeed partially oxidized.
- Inorganic Chemistry
- Organic Chemistry