Accession Number:

ADA059642

Title:

Rational Synthesis of Unidimensional Mixed Valence Solids. Structure-Oxidation State-Charge Transport Relationships in Iodinated Nickel and Palladium Bisbenzoquinonedioximates.

Descriptive Note:

Technical rept.,

Corporate Author:

NORTHWESTERN UNIV EVANSTON ILL DEPT OF CHEMISTRY

Report Date:

1978-08-22

Pagination or Media Count:

68.0

Abstract:

The results of the present investigation indicate that the Mbqd2I0.50 materials, M Ni, Pd, are best formulated as Mbqd2I0.50.S materials where S represents various amounts of the aromatic solvent employed for crystallization. As deduced from resonance Raman, I-129 Mossbauer, and diffuse x-ray scattering measurements, the iodine is present as I3-, and thus the mbqd2I0.50.S materials are indeed partially oxidized.

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE