Synthesis and Properties of Several New Molecular Conductors.
VERMONT UNIV BURLINGTON DEPT OF CHEMISTRY
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Several d superscript 8 metal complexes with columnar structures have been prepared using diaminoglyoxime, rubeanic acid, dithiooxalate, and dimethylglyoxime as ligands. These compounds are susceptible to partial oxidation using a variety of electron acceptors such as iodine and quinone. Upon oxidation, the electrical conductivities of these materials increase by as much as eleven orders of magnitude. The role of intermolecular association in the preparation of an excitonic superconductor is discussed. Author
- Inorganic Chemistry
- Organic Chemistry