Accession Number:

ADA058042

Title:

Ligand and Solvent Effects on Emission Lifetimes of Cr(III) Ammines.

Descriptive Note:

Technical rept.,

Corporate Author:

UNIVERSITY OF SOUTHERN CALIFORNIA LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1978-07-01

Pagination or Media Count:

29.0

Abstract:

Emission lifetimes and their temperature dependence are reported for a number of CRIII ammine complexes. A new set of rules governing emission from room temperature, fluid solution is proposed. A rationale for the rules is that thermal-type photosubstitution occurs from the First thexi doublet state and that the rate controls the lifetime. Author

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE