Tetrametallic Nickel-Boron Clusters, (ETA to the 5th power-C5H5)4Ni4B4H4 and (ETA to the 5th power-C5H5)4Ni4B5H5, by transition metal aggregation on a small Borane framework
VIRGINIA UNIV CHARLOTTESVILLE DEPT OF CHEMISTRY
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The reaction of NaB5H8- with nickelocene and sodium amalgam in tetrahydrofuran at ambient temperature yielded the title compounds, which were isolated as crystalline solids and characterized from their B11 and H FT NMR and mass spectra and an X-ray structure determination of the Ni4B4 cluster.
- Inorganic Chemistry
- Organic Chemistry