Calculation of the Laser Induced Stark Shifts in Diatomic Molecules.
Final rept. 1 Sep 75-30 Sep 76,
MARYLAND UNIV COLLEGE PARK INST FOR PHYSICAL SCIENCE AND TECHNOLOGY
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Standard perturbation results are applied to the case of laser induced dynamic Stark shifts of vibration-rotation terms of diatomic molecules. For fields at frequencies near an allowed vibration-rotation transition there are just four terms coupled by allowed transitions which cause significant shifts. After discussion of the method of calculating specific matrix elements from rotationless Einstein A coefficients, examples are of Stark shift predictions for terms of HF, DF and CO involved in strong laser lines of these molecules. Author
- Atomic and Molecular Physics and Spectroscopy
- Quantum Theory and Relativity