A Ligand Field Theory Analysis of the Spectra of the t2g3 Levels of IrF6.
COLORADO STATE UNIV FORT COLLINS DEPT OF CHEMISTRY
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Calculations are presented for the t2g3 molecular levels of IrF6 which indicate a substantial interaction with charge transfer levels at ca. 20,000cm. Interaction between charge transfer and t2g states is so extensive that the five t2g3 levels cannot be fit with physically reasonable Racah, spin orbit, and crystal field parameters.
- Inorganic Chemistry
- Atomic and Molecular Physics and Spectroscopy