Analytical Implications of Differential Pulse Polarography of Irreversible Reactions from Digital Simulation; Calculations and Experiments.
COLORADO STATE UNIV FORT COLLINS DEPT OF CHEMISTRY
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Explicit finite difference simulations of differential pulse polarography have been developed for evaluating the analytical applications of differential pulse polarography to irreversible and quasireversible electron transfer reactions. From simulation data, detailed prediction of polarographic peak shape and position as a function of pulse height, pulse time and drop time is possible. Optimum conditions for analytical application of differential pulse polarography are discussed. Author
- Physical Chemistry
- Numerical Mathematics