The Molybdenum-to-Molybdenum Triple Bond. 5. Preparation and Structure of Dimethyltetrakis(dimethylamido)dimolybdenum.
PRINCETON UNIV N J DEPT OF CHEMISTRY
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The existence of an extensive chemistry centering around the triplybonded Mo-Mo and W-W units is now well established and has recently been reviewed. A firm structural base for interpreting this chemistry has been provided by more than a score of x-ray crystallographic structure determinations. Among these, however, there have been only a few pairs of molybdenum and tungsten compounds with the same or very similar sets of ligands. The comparisons afforded by such pairs are valuable in developing the comparative chemistry of the M-M multiple bonds in the 2nd and 3rd transition series. Author
- Inorganic Chemistry