Accession Number:

ADA048223

Title:

Physical and Chemical Properties of Squarate Complexes. I. Spectral, Magnetic, and Thermal Behavior of Dimeric Iron(III) Squarate.

Descriptive Note:

Technical rept.,

Corporate Author:

VERMONT UNIV BURLINGTON DEPT OF CHEMISTRY

Personal Author(s):

• Wrobleski,James T.
• Brown,David B.

Report Date:

1977-12-08

Pagination or Media Count:

16.0

Abstract:

The magnetic susceptibility behavior of an ironIII squarate complex with empirical formula FeC404OHH2O3 has been studies in the range 20-300K. Presence of both terminally-coordinated bidentate squarate dianion and bridging hydroxy groups is supported by the infrared spectrum of the dimer.

Descriptors:

• *PHYSICOCHEMICAL PROPERTIES
• *METAL COMPLEXES
• *IRON ORGANIC COMPOUNDS
• THERMAL PROPERTIES
• MAGNETIC PROPERTIES
• MOSSBAUER EFFECT
• LIGANDS
• MOLECULAR STRUCTURE
• ABSORPTION SPECTRA
• ANIONS
• INFRARED SPECTRA
• DIMERS
• HYDROXYL RADICALS

Subject Categories:

• Polymer Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE