Synthesis of Novel Inorganic Fluorine Compounds by Direct Fluorination.
MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY
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It has been found possible to preserve metal-carbon and metalloid-carbon bonds during direct fluorination. The reaction of dimethylmercury with fluorine gives bistrifluoromethylmercury in 6.5 yield. Fluorination of tetramethylsilane has led to the isolation of the new polyfluorotetramethylsilanes of the following type, SiCH3xCH2FyCHF2z, xyz 4. Also characterized were compounds containing Si-CF3. It has been possible to synthesize tetrakistrifluoromethylgermanium in 63,5 yield from the reaction of fluorine with tetramethylgermanium. Also characterized were many polyfluorotetramethylgermanes of the following type, GeCF3xCF2HyCFH2z, z y z 4. Author
- Inorganic Chemistry
- Organic Chemistry