Accession Number:

ADA043037

Title:

Synthesis of Novel Inorganic Fluorine Compounds by Direct Fluorination.

Descriptive Note:

Final rept.,

Corporate Author:

MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1977-07-28

Pagination or Media Count:

57.0

Abstract:

It has been found possible to preserve metal-carbon and metalloid-carbon bonds during direct fluorination. The reaction of dimethylmercury with fluorine gives bistrifluoromethylmercury in 6.5 yield. Fluorination of tetramethylsilane has led to the isolation of the new polyfluorotetramethylsilanes of the following type, SiCH3xCH2FyCHF2z, xyz 4. Also characterized were compounds containing Si-CF3. It has been possible to synthesize tetrakistrifluoromethylgermanium in 63,5 yield from the reaction of fluorine with tetramethylgermanium. Also characterized were many polyfluorotetramethylgermanes of the following type, GeCF3xCF2HyCFH2z, z y z 4. Author

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE