Accession Number:

ADA036681

Title:

Unusual Metalloporphyrins, Phosphorus Complexes of Tetraphenylporphine.

Descriptive Note:

Interim rept.,

Corporate Author:

TEXAS A AND M UNIV COLLEGE STATION DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1977-01-01

Pagination or Media Count:

16.0

Abstract:

The synthesis and spectral properties of several phosphorus complexes of tetraphenylporphine TTP are reported. The compounds appear to have the form TPPPVX2Y- as previously reported by Gouterman et al. for the analogous octaethylporphyrin OEP complexes. The electronic and nmr spectra show a striking dependence on the nature of the anionic ligand X, which has not previously been reported and appears to be inconsistent with a symmetrical in-plane structure. Author

Subject Categories:

  • Organic Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE