Unusual Metalloporphyrins, Phosphorus Complexes of Tetraphenylporphine.
TEXAS A AND M UNIV COLLEGE STATION DEPT OF CHEMISTRY
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The synthesis and spectral properties of several phosphorus complexes of tetraphenylporphine TTP are reported. The compounds appear to have the form TPPPVX2Y- as previously reported by Gouterman et al. for the analogous octaethylporphyrin OEP complexes. The electronic and nmr spectra show a striking dependence on the nature of the anionic ligand X, which has not previously been reported and appears to be inconsistent with a symmetrical in-plane structure. Author
- Organic Chemistry
- Atomic and Molecular Physics and Spectroscopy