Reactions between AlO Sub x and O Atoms.
Final technical rept. 24 Nov 75-23 Oct 76,
AEROCHEM RESEARCH LABS INC PRINCETON N J
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Rate coefficients for the reactions AlO O yields Al O2, AlO2 O yields AlO O2, Al SO2 yields AlO SO and Al NO M yields AlNO M from high-temperature fast flow reactor HTFFR measurements are reported. DAl-O was determined to be or 126 kcalmole. Emission of chemiluminescence continua 280 nm to 725 nm in mixtures of atomic Al with i O atoms and ii N atoms occurs, via not yet elucidated addition mechanisms, with a rate coefficient of 10 to the -12th power to 10 to the -11th power mlmoleculesec. Author
- Atomic and Molecular Physics and Spectroscopy