Synthesis and Characterization of Seven-Coordinate Hydro-Complexes of Ruthenium with Carborane: 2-1-7- and 3-1-2-(P(C6H5)3)RuH2C2B9H11.
CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY
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Oxidative addition of 7-8- and 7-9-C2B9H12- to PC6H53RuHcl have yielded novel dihydrido-ruthenium complexes 3-1-2- and 2-1-7-PC6H53RuH2C2B9H11 respectively the latters structure has been confirmed by x-ray diffraction study and it has been found to reversibly eliminate its hydride ligands as H2 upon heating in vacuum. Author
- Organic Chemistry