Accession Number:

ADA025864

Title:

Salt-Type Complexes of Porphyrins: Monocation Octaethyl Porphinium Tri-u-halogeno-hexacarbonyldirhenate (I).

Descriptive Note:

Technical rept.,

Corporate Author:

TEXAS A AND M UNIV COLLEGE STATION DEPT OF CHEMISTRY

Report Date:

1976-05-26

Pagination or Media Count:

13.0

Abstract:

The synthesis and characterization of a monocationic porphyrin species which includes a new anionic halogenocarbonyl rhenium I species as the cation are reported. By the reation of a 21 mole ration of rhenium pentacarbonyl chloride and octaethylporphine in refluxing decalin under argon, both the dirhenium octaethylporphine, OEPReCO32, and a salt-type complex of H3OEPRe2CO6Cl3,-cO6 were synthesized. X-ray structural analysis of the salt-type complex revealed an unusual structure of the anionic halogenocarbonyl rhenium I species complex with an octaethylporphinium monocation. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE